Philip J. Squattrito
Professor of Chemistry
356 Dow Science Building
Telephone: 989-774-4407
Email: p.squattrito@cmich.edu
Education
Work History
- Postdoctoral Associate, Texas A&M University (1986-1989)
- Assistant Professor, Central
Michigan University (1989-1994)
- Associate Professor, Central
Michigan University (1994-1998)
- Professor, Central Michigan University
(1998- )
Teaching
- General Chemistry (CHM 131, 132,
161H)
- Inorganic Chemistry (CHM 331,
531, 676)
- Solid State Chemistry (CHM 571/632)
Some scenes from CHM 161H Fall 2001
Research Interests
- Structural inorganic chemistry
and X-ray crystallography
- Mixed inorganic-organic compounds
with layered or framework structures
- Sulfonic acids and metal sulfonate
salts
- Metal triazole complexes
- Inclusion chemistry
trans-diaquabis(4-amino-1,2,4-triazole-5-thione)cobalt(II)
cis-diaquabis(4-amino-3-methyl-1,2,4-triazole-5-thione)cobalt(II)
A scene from the X-ray crystallography laboratory
Professional Memberships
University Service
- Member, CMU Radiation Safety
Committee
- Department of Chemistry Graduate
Program Coordinator
- Membership Officer, CMU Faculty
Association
Professional Service
With doctoral advisor Jim Ibers at Northwestern University,
May 2002
Recent Publications
- "Hexaaquametal(II) 4-Styrenesulfonates of Manganese,
Cobalt, and Nickel", Melvin A. Leonard, Philip J. Squattrito, and Surendra
N. Dubey, Acta Crystallogr., Sec. C 55, 35 (1999).
- "Structure of a Cs(18-Crown-6)N(CN)2.H2O Complex: Assembly
of the Dimeric 2:2 Anion Paired Encapsulate by Means of m2-Bridge Function
of the Water Molecules", Julia A. Rusanova, Philip J. Squattrito, Konstantin
V. Domasevitch, and Volodimir N. Kokozay, Z. Naturforschung54b,
389 (1999).
- "Synthesis and Characterization of Complexes
of Cobalt(II), Nickel(II), Copper(II) and Zinc(II) with Schiff Bases Derived
from Cinnamaldehyde and 4-Amino-3-ethyl-5-mercapto-s-triazole and
4-Amino-5-mercapto-3-N-propyl-s-triazole", A. Kumar, G. Singh,
R. N. Handa, S. N. Dubey and P. J. Squattrito, Indian J. Chem. 38A,
613 (1999).
- "Wrap-Around Encapsulated Cs(dibenzo-24-crown-8)+ Cations Form Linear Coordination Polymer with Dicyanoargentate
Anion Ag(CN)2-", Julia A. Rusanova, Philip
J. Squattrito, Vera V. Ponomareva, Konstantin V. Domasevitch and Volodimir
N. Kokozay, Z. Naturforschung 54b, 1129 (1999).
- "Structural Trends in a Series of Divalent Transition
Metal Triazole Complexes", Robert W. Clark, Philip J. Squattrito, Ashok K.
Sen, and Surendra N. Dubey, Inorg. Chim. Acta 293, 61 (1999).
- "Extended Multidecker Sandwich Architecture of
Cs+-18-crown-6 Complexes Stabilized in
the Environment of Novel Large Iodocuprate(I) Clusters Obtained From Zerovalent
Copper", K.V. Domasevitch, J.A. Rusanova, O.Yu. Vassilyeva, V.N. Kokozay,
P.J.Squattrito, J. Sieler and P.R. Raithby, J. Chem. Soc. Dalton
Trans., 3087 (1999).
- "Two Schiff Base Derivatives of 4-Amino-3-propyl-1,2,4-triazole-5-thione",
Robert M. McCarrick, Philip J. Squattrito, Rajkumar Noren Singh, Ram N. Handa
and Surendra N. Dubey, Acta Crystallogr., Sec. C 55, 2111 (1999).
- "cis- and trans-Dichloro(3,6-dihydro-1,2-oxazine-N)(dimethyl
sulfoxide-S)platinum(II)", R. Max Dyksterhouse, Bob A. Howell, and
Philip J. Squattrito, Acta Crystallogr., Sec. C 56, 64 (2000).
- "Coordination geometries of bis(4-amino-3-ethyl-1,2,4-triazole-5-thione)
complexes of Mn, Fe, Co, Ni, Cu, and Zn: relationship to the 3-methyl analogs",
Todd W. Kajdan, Philip J. Squattrito and Surendra N. Dubey, Inorg.
Chim. Acta 300-302, 1082 (2000).
- "4-Fluoro-2-(phosphonomethyl)benzenesulfonic
Acid Monohydrate", Fabrizio Adani, Enzo Montoneri and Philip J. Squattrito,
Acta Crystallogr., Sec. C 56, 463 (2000).
- "cis-Bis(3,6-dihydro-2H-1,2-oxazine-N)diiodoplatinum(II)
and cis-Bis(3,4,5,6-tetrahydro-2H-1,2-oxazine-N)diiodoplatinum(II)",
Jennifer A. Saltmarsh, Bob A. Howell and Philip J. Squattrito, Acta Crystallogr.,
Sec. C56, e335 (2000).
- "Coordination geometries of bis(4-amino-3-alkyl-1,2,4-triazole-5-thione)
complexes of first row transition metals: Crystal structures of complexes
with propyl and hydrogen in the 3-position. Relationship to the 3-methyl
and 3-ethyl analogs", Robert M. McCarrick, Martin J. Eltzroth, Philip
J. Squattrito, Inorg. Chim. Acta311, 95 (2000).
- "Structure Determination of a Twinned Rb(H2NC10H6SO3).H2O Crystal and Comparison to
Related Alkali Metal Aminonaphthalenesulfonates", Anthony Martin, Damon
Parrish, A. Alan Pinkerton, Brian J. Gunderman, and Philip J. Squattrito,
Z. Anorg. Allg. Chem.627, 206 (2001).
- "Coordination geometries of bis(4-amino-3-alkyl-1,2,4-triazole-5-thione)
complexes of first row transition metals: Crystal structures of the cobalt
and nickel complexes of 4-amino-3-trifluoromethyl-1,2,4-triazole-5-thione",
Christopher M. Menzies and Philip J. Squattrito, Inorg. Chim. Acta 314,
194 (2001).
- "Symmetric and Asymmetric Trinuclear Cores in
Novel m-Alkoxo-Bridged Mixed-Metal CuII2ZnII Complexes: Synthesis From Zerovalent
Copper and Zinc Oxide, Structure and Magnetism", Elena A. Vinogradova, Olga
Yu. Vassilyeva, Volodymyr N. Kokozay, Philip J. Squattrito, Jan Reedijk,
Gerard A. Van Albada, Wolfgang Linert, Satish K. Tiwary, and Paul R. Raithby,
New J. Chem. 25, 949 (2001).
- “Structures of Divalent Transition Metal Salts of 4-Aminonaphthalene-1-sulfonate:
Unexpected Variations in Layering Pattern”, Jill E. Morris, Philip J. Squattrito,
Kristin Kirschbaum and A. Alan Pinkerton, J. Chem. Crystallogr. 33,
307 (2003).
Recent Students
- Robert W. Clark, doctoral student
in chemistry at the University of Wisconsin,
Madison WI
- Todd W. Kajdan, chemist at the
Dow Chemical Company,
Midland MI
- Benjamin J. Vesper, doctoral
student in chemistry at Northwestern
University, Evanston IL
- Robert M. McCarrick,
doctoral student in chemistry at the University
of Michigan, Ann Arbor MI
- La Keya A. Belcher, masters student
in chemical engineering at Michigan State
University, East Lansing MI
- Christopher M. Menzies, chemist at the Dow Chemical Company, Midland
MI
- Martin J. Eltzroth, chemistry instructor at Mid-Michigan Community
College, Harrison MI
- Melvin A. Leonard, pharmacist in Port Huron MI
- Jill E. Morris, doctoral student in chemistry at Michigan
State University, East Lansing MI
- Alvin Kalinda, masters student in chemistry at Central Michigan University, Mt. Pleasant
MI